Materials Analysis Using a THz Imaging System Based on Atomic Vapour

This thesis studies the response of the interaction between Rydberg atomic vapour and a THz frequency field. When Caesium atoms at room temperature are excited to a Rydberg state using three infrared lasers and a 0.55 THz field resonant with the 14P3/2 → 13D5/2 transition is applied, the atoms respond by emitting a green optical fluorescence corresponding to the 13D5/2 → 6P3/2 decay. This response is exploited to investigate the absorption coefficient for different polymer materials that transmit well in the THz frequency range using the Beer–Lambert law. We calibrate the system to obtain a measure of THz intensity. As the THz imaging system is highly sensitive to environmental changes, and to show that our results are consistent, we provide a comparison of results between our atomic detection method and a commercial thermal power meter. Additionally, we measure the absorption coefficient of the same materials at a frequency of 1.1 THz, and the results are compared with those measured at 0.55 THz. The THz imaging system is also used to perform some experiments in order to demonstrate its effectiveness in real-world applications. The system provides an interesting image contrast in the case of a sample containing two different polymer materials measured at two THz frequencies. The result is a proof-of-concept that multispectral THz imaging can provide additional information and is motivation to improve our THz imaging system by introducing a dual-species THz imager. We also investigate the polarisation spectroscopy of an excited-state transition of rubidium vapour at room temperature as a step towards a rubidium THz imaging system. The narrow dispersive signal produced by this spectroscopy technique is ideal for laser frequency stabilisation of excited-state transitions.